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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds - nuovo libro

ISBN: 9783709113165

This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and … Altro …

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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds - Okamoto, Hiroshi (Herausgeber); Yamashita, Masahiro (Herausgeber)
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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds - copertina rigida, flessible

2012, ISBN: 3709113164

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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds - libri usati

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ISBN: 9783709113165

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Yamashita, Masahiro und Hiroshi Okamoto:
Material Designs and New Physical Properties in MX- and MMX-Chain Compounds 2013 - libri usati

2012, ISBN: 9783709113165

2013 Buchschnitt verkürzt- gepflegter, sauberer Zustand - Ausgabejahr 2013 22557033/12 Versandkostenfreie Lieferung mixed valence,MMX compounds,Halogen bridged,MX compounds,, [PU:Springer… Altro …

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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds - copertina rigida, flessible

2013, ISBN: 3709113164

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Dettagli del libro
Material Designs and New Physical Properties in MX- and MMX-Chain Compounds

This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.

Informazioni dettagliate del libro - Material Designs and New Physical Properties in MX- and MMX-Chain Compounds


EAN (ISBN-13): 9783709113165
ISBN (ISBN-10): 3709113164
Copertina rigida
Anno di pubblicazione: 2012
Editore: Springer Wien
350 Pagine
Peso: 0,532 kg
Lingua: Englisch

Libro nella banca dati dal 2009-12-13T02:22:29+01:00 (Zurich)
Pagina di dettaglio ultima modifica in 2024-01-16T13:09:58+01:00 (Zurich)
ISBN/EAN: 3709113164

ISBN - Stili di scrittura alternativi:
3-7091-1316-4, 978-3-7091-1316-5
Stili di scrittura alternativi e concetti di ricerca simili:
Autore del libro : hiro, yamashita, hiroshi okamoto, masahiro, strong nonlinear
Titolo del libro: physica, material material, properties, designs


Dati dell'editore

Autore: Masahiro Yamashita; Hiroshi Okamoto
Titolo: Material Designs and New Physical Properties in MX- and MMX-Chain Compounds
Editore: Springer; Springer Wien
270 Pagine
Anno di pubblicazione: 2012-12-14
Vienna; AT
Stampato / Fatto in
Peso: 0,604 kg
Lingua: Inglese
106,99 € (DE)
109,99 € (AT)
118,00 CHF (CH)
POD
X, 270 p.

BB; Organometallic Chemistry; Hardcover, Softcover / Chemie/Organische Chemie; Metallorganische Chemie; Verstehen; Halogen bridged; MMX compounds; MX compounds; mixed valence; Optical and Electronic Materials; Medicinal Chemistry; Inorganic Chemistry; Organometallic Chemistry; Optical Materials; Medicinal Chemistry; Inorganic Chemistry; Technische Anwendung von elektronischen, magnetischen, optischen Materialien; Medizinische Chemie, Pharmazeutische Chemie; Anorganische Chemie; BC; EA

This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.

S. Takaishi and M. Yamashita H. Matsuzaki and H. Okamoto S. Takaishi and M. Yamashita S. Takaishi and M. Yamashita H. Matsuzaki and H. Okamoto H. Kishida and A. Nakamura H. Kishida and H. Okamoto K. Iwano M. Mitsumi H. Iguchi, S. Takaishi and M. Yamashita H. Matsuzaki and H. Okamoto K. Yonemitsu.

Low-dimensional semiconductors with exciting optical properties are extensively discussed

Physical properties arising from quasi-one-dimensional electronic systems are covered

Various photoinduced phase transitions and their dynamics are presented

Includes supplementary material: sn.pub/extras



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